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  • Title: Oxidation-reduction transformations of chromium in aerobic soils and the role of electron-shuttling quinones.
    Author: Brose DA, James BR.
    Journal: Environ Sci Technol; 2010 Dec 15; 44(24):9438-44. PubMed ID: 21105643.
    Abstract:
    Oxidation of Cr(III) and reduction of Cr(VI) can occur simultaneously in aerobic soils, but the mechanisms involved are not well-understood, especially how electron shuttling by redox-active organic acids is involved. A and B soil horizons from three topohydrosequences from the Coastal Plain and Piedmont physiographic provinces of Maryland were chosen to investigate oxidation-reduction transformations of Cr under field moist conditions. Reduction of added Cr(VI) to Cr(III) was observed in all 18 samples, and 11 demonstrated enhanced reduction with added anthraquinone-2,6-disulfonate (AQDS) acting as an electron shuttle in 24 h quick tests under aerobic conditions. Oxidation of Cr(III) to Cr(VI) was observed in 12 samples, with 7 demonstrating diminished oxidation with AQDS added. Cr(VI) was undetectable after 11 d of incubation when lactic acid was added as a reductant for Cr(VI) to the Watchung soil A horizon. This reduction occurred in the presence of AQDS and a high salt background to suppress microbial growth, suggesting abiotic reduction was the dominant pathway. The results of this study demonstrate that in field-moist, aerobic soils, the electron shuttle, AQDS, enhanced Cr(VI) reduction and inhibited Cr(III) oxidation. This suggests redox-active organic C amendments and electron shuttles can be important in enhancing rates and extent of Cr(VI) reduction, while inhibiting Cr(III) oxidation in the in situ remediation of Cr(VI)-contaminated soils.
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