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  • Title: Stereoselective palladium-catalyzed allylic alkylations of peptide amide enolates.
    Author: Datta S, Kazmaier U.
    Journal: Org Biomol Chem; 2011 Feb 07; 9(3):872-80. PubMed ID: 21125093.
    Abstract:
    Pd-catalyzed allylations are an excellent tool for stereoselective peptide modifications, being clearly superior to normal alkylations. The reactions proceed not only in high yield, but also high regio- and diastereoselectivities, and trans-products are formed exclusively. Therefore, this is a powerful synthetic tool for natural product and drug synthesis.
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