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  • Title: Alkene isomerization/enamide-ene and diene metathesis for the construction of indoles, quinolines, benzofurans and chromenes with a chiral cyclopropane substituent.
    Author: Kobayashi T, Arisawa M, Shuto S.
    Journal: Org Biomol Chem; 2011 Feb 21; 9(4):1219-24. PubMed ID: 21180704.
    Abstract:
    A synthetic method for bicyclic heterocycles, such as indole, benzofuran and chromene derivatives bearing a chiral cyclopropane at the 2-position, was established using isomerization of a terminal olefin and enamide-ene or diene metathesis. This route can also be applied to chiral 2-cyclopropylquinoline synthesis (both cis and trans).
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