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  • Title: Synthesis of 2-azaanthracenes via a sequential Sonogashira coupling/alkynyl imine-allenyl imine isomerization/aza-Diels-Alder/elimination-aromatization reaction.
    Author: Cao J, Yang X, Hua X, Deng Y, Lai G.
    Journal: Org Lett; 2011 Feb 04; 13(3):478-81. PubMed ID: 21182265.
    Abstract:
    An interesting sequential Sonogashira coupling/alkynyl imine-allenyl imine isomerization/aza-Diels-Alder/elimination-aromatization reaction, providing a facile synthesis of substituted 2-azaanthracenes from 1,6-diynes and imidoyl chlorides, is reported. The easy procedure accessing the products efficiently from readily available starting materials may imply a potential synthetic application.
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