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  • Title: Total synthesis of broussonetine F: the orthoamide Overman rearrangement of an allylic diol.
    Author: Hama N, Aoki T, Miwa S, Yamazaki M, Sato T, Chida N.
    Journal: Org Lett; 2011 Feb 18; 13(4):616-9. PubMed ID: 21194237.
    Abstract:
    A first total synthesis of broussonetine F from diethyl L-tartrate was achieved. The cornerstone of our synthesis was an orthoamide Overman rearrangement, which provided an allylic amino alcohol with complete diastereoselectivity.
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