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  • Title: Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment.
    Author: Takaki D, Okayama T, Shuto H, Matsumoto S, Yamaguchi Y, Matsumoto S.
    Journal: Dalton Trans; 2011 Feb 21; 40(7):1445-7. PubMed ID: 21234495.
    Abstract:
    Indenyl-functionalised BEt(3)-adduct NHCs were prepared by the reaction of imidazolium pro-ligands with LiBEt(3)H. This compound was converted into the indenyl-coordinate molybdenum complex dangling the NHC·BEt(3) moiety as a substituent. The stepwise coordination of NHC afforded a chelate-type mononuclear complex as well as a bimetallic complex.
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