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  • Title: Palladium-catalyzed selective acyloxylation using sodium perborate as oxidant.
    Author: Pilarski LT, Janson PG, Szabó KJ.
    Journal: J Org Chem; 2011 Mar 04; 76(5):1503-6. PubMed ID: 21250717.
    Abstract:
    Sodium perborate (SPB), a principal component of washing powders, was employed as an inexpensive and eco-friendly oxidant in the palladium-catalyzed C-H acyloxylation of alkenes in excellent regio- and stereochemistry. The reactions used anhydrides as acyloxy sources. The method applies to both terminal and internal alkenes, and even benzylic C-H oxidation.
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