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Title: Novel molecularly imprinted polymer using 1-(α-methyl acrylate)-3-methylimidazolium bromide as functional monomer for simultaneous extraction and determination of water-soluble acid dyes in wastewater and soft drink by solid phase extraction and high performance liquid chromatography.
Author: Luo X, Zhan Y, Tu X, Huang Y, Luo S, Yan L.
Journal: J Chromatogr A; 2011 Feb 25; 1218(8):1115-21. PubMed ID: 21251659.
Abstract:
Novel water-compatible molecularly imprinted polymers were synthesized in methanol-water systems with Tratarzine as template and 1-(α-methyl acrylate)-3-methylimidazolium bromide (1-MA-3MI-Br) as functional monomer, which has π-π hydrophobic, hydrogen-bonding and electrostatic interactions with template molecule. 1-MA-3MI-Br molecularly imprinted polymers (1-MA-3MI-Br-MIPs) were used as selective sorbents for the solid-phase extraction (SPE) of water-soluble acid dyes from wastewater and soft drink. The good linearity of the method was obtained in a range of 5.0-2000 μg/L with the correlation coefficient of > 0.999. The detection limits were in a range of 0.13-0.51 μg/L for the water-soluble acid dyes in wastewater and 0.095-0.84 μg/L for those in soft drink. The mean recoveries for the acid dyes are from 89.1% to 101.0% in spiked wastewater and 91.0-101.3% in spiked soft drink. Compared with strongly anion exchange solid phase extraction (SAX-SPE), mixture anion exchange solid phase extraction (MAX-SPE), and 1-MA-3MI-Br non-imprinted solid phase extraction (1-MA-3MI-Br-NISPE), almost all of the matrix interferences were removed by 1-MA-3MI-Br-MISPE, exhibiting higher selectivity, recovery and enrichment ability for the acid dyes and better baselines in the results of HPLC analysis.

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