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  • Title: Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes.
    Author: Patureau FW, Besset T, Kuhl N, Glorius F.
    Journal: J Am Chem Soc; 2011 Feb 23; 133(7):2154-6. PubMed ID: 21265571.
    Abstract:
    The synthesis of indenols and fulvenes was achieved through Rh-catalyzed C-H bond activation of simple and diverse aryl ketone derivatives and subsequent coupling with internal alkynes. The process was found to involve either an α or γ dehydration step, depending on the substrate disposition and representing diverse pathways toward functionalized fulvenes.
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