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  • Title: Toward the second generation synthesis of aplyronine A: stereocontrolled assembly of the C1-C19 segment by using an asymmetric Nozaki-Hiyama-Kishi coupling.
    Author: Kobayashi K, Fujii Y, Hayakawa I, Kigoshi H.
    Journal: Org Lett; 2011 Mar 04; 13(5):900-3. PubMed ID: 21268638.
    Abstract:
    An efficient synthesis of the C1-C19 segment of aplyronine A is described. Stereoselective construction of the C14-C15 (E)-trisubstituted double bond and the C13 stereocenter was achieved by using an asymmetric Nozaki-Hiyama-Kishi coupling.
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