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Title: Design, synthesis, and insecticidal activities of novel monohalovinylated pyrethroids. Author: Zheng Z, Wang J, Zhang D, Guan X, Gao S, Chen Z, Zou X. Journal: J Agric Food Chem; 2011 Feb 23; 59(4):1171-7. PubMed ID: 21275401. Abstract: A series of novel monohalovinylated pyrethroids are designed and synthesized to replace one halo atom with a hydrogen atom on the double bond of dihalopyrethroids. Bioassays indicate that some of the synthesized compounds, such as 3j and 1j, exhibit high insecticidal activities against mosquitoes ( Culex pipiens pallens ), oriental armyworms ( Mythimna separata ), alfalfa aphids ( Aphis medicagini ), and carmine spider mites ( Tetranychus cinnabarinus ). Photolytic results of E-cis-1j suggest that monohalovinylated pyrethroids are photodegraded more easily than compound 12.[Abstract] [Full Text] [Related] [New Search]