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  • Title: Highly enantioselective synthesis of polysubstituted tetrahydroquinolines via organocatalytic Michael/Aza-Henry tandem reactions.
    Author: Jia ZX, Luo YC, Xu PF.
    Journal: Org Lett; 2011 Mar 04; 13(5):832-5. PubMed ID: 21288007.
    Abstract:
    Highly enantioselective chiral bifunctional thiourea catalyzed asymmetric tandem reactions for synthesis of substituted tetrahydroquinolines are described. Substituted tetrahydroquinolines were given in good yields (up to 98%), high enantioselectivities (up to >99% ee), and diastereoselectivities (up to 20:1 dr).
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