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  • Title: Observable temperature-dependent compaction-decompaction of cationic polythiophene in the presence of iodide.
    Author: Wang J, Zhang Q, Tan KJ, Long YF, Ling J, Huang CZ.
    Journal: J Phys Chem B; 2011 Feb 24; 115(7):1693-7. PubMed ID: 21288043.
    Abstract:
    Investigation on compaction and decompaction of polymers is very important since it is a fundamental problem in polymer physics. With the aids of atomic force microscope (AFM) and dynamic light scattering (DLS) measurements in this contribution, the temperature-dependent compaction/decompaction transition process of water-soluble cationic polythiophene (PT) was investigated in the presence of KI. The above process is characterized by the red-to-yellow color change and fluorescence recovery and is reversible during the heating-cooling cycles in the range from 25 to 55 °C, indicating that the compaction and decompaction of polymer can be employed as a temperature indicator.
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