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  • Title: N-heterocyclic carbene Pt(II) complexes from caffeine: synthesis, structures and photoluminescent properties.
    Author: Hu JJ, Bai SQ, Yeh HH, Young DJ, Chi Y, Hor TS.
    Journal: Dalton Trans; 2011 May 07; 40(17):4402-6. PubMed ID: 21409198.
    Abstract:
    The caffeine-derived N-heterocyclic carbene (NHC) complex [Pt(II)(C^N)(NHC)Cl] (C^N = 2-phenylpyridine), 4 has the opposite stereochemistry and a shorter Pt-C(carbene) bond compared to that of an analogous benzimidazole-derived N,N-heterocyclic carbene (NNHC) Pt complex 2. These suggest a lower trans influence of pyridyl N compared to cyclometallated carbon and an increased Pt-NHC π-backbonding because of decreased π-donation resulting from conjugation to the electron deficient pyrimidine of caffeine. Complex 4 has a lower emission quantum yield (Φ) and is blue-shifted into the green region of the visible spectrum relative to non-carbene Pt(II) cyclometalated complex 5.
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