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  • Title: Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide.
    Author: Shen ZL, Goh KK, Wong CH, Yang YS, Lai YC, Cheong HL, Loh TP.
    Journal: Chem Commun (Camb); 2011 Apr 28; 47(16):4778-80. PubMed ID: 21412540.
    Abstract:
    An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into β-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.
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