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  • Title: Addition of boranes to N-aryl-salicylaldimines: intramolecular hydrogenation of imines.
    Author: Barnes SS, Vogels CM, Decken A, Westcott SA.
    Journal: Dalton Trans; 2011 May 07; 40(17):4707-14. PubMed ID: 21431160.
    Abstract:
    Addition of boranes to N-aryl-salicylaldimines takes place initially at the reactive phenolic O-H bond to give an activated boron-containing imine and dihydrogen. In some cases a subsequent intramolecular hydrogenation step is observed and the C=N imine bond is reduced to the corresponding amine. Reactions with dimesitylborane in THF are unique in that the reduced amine product is the major product observed in solution.
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