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  • Title: Nanoporous network channels from self-assembled triblock copolymer supramolecules.
    Author: du Sart GG, Vukovic I, Vukovic Z, Polushkin E, Hiekkataipale P, Ruokolainen J, Loos K, ten Brinke G.
    Journal: Macromol Rapid Commun; 2011 Feb 16; 32(4):366-70. PubMed ID: 21433185.
    Abstract:
    Supramolecular complexes of a poly(tert-butoxystyrene)-block-polystyrene-block-poly(4-vinylpyridine) triblock copolymers and less than stoichiometric amounts of pentadecylphenol (PDP) are shown to self-assemble into a core-shell gyroid morphology with the core channels formed by the hydrogen-bonded P4VP(PDP)complexes. After structure formation, PDP was removed using a simple washing procedure, resulting in well-ordered nanoporous films that were used as templates for nickel plating.
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