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  • Title: Organocatalytic trifluoromethylation of imines using phase-transfer catalysis with phenoxides. A general platform for catalytic additions of organosilanes to imines.
    Author: Bernardi L, Indrigo E, Pollicino S, Ricci A.
    Journal: Chem Commun (Camb); 2012 Feb 01; 48(10):1428-30. PubMed ID: 21479321.
    Abstract:
    A new approach to additions of silicon nucleophiles to imines was developed. The method is based on the phase-transfer of phenoxides by ammonium catalysts, overcoming the inability of amide adducts in promoting the reactions.
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