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  • Title: Current progress on the chemical functionalization and supramolecular chemistry of M@C82.
    Author: Maeda Y, Tsuchiya T, Lu X, Takano Y, Akasaka T, Nagase S.
    Journal: Nanoscale; 2011 Jun; 3(6):2421-9. PubMed ID: 21483901.
    Abstract:
    Since the first discovery of fullerenes in 1985, the insertion of one or more atoms into a hollow fullerene cage has been attempted. Furthermore, synthesis and extraction of metallofullerene, La@C(n), were reported in 1991. Recent successful isolation and purification of metallofullerenes have facilitated the investigation of their chemical properties. This mini-review presents a summary of the recent progress of chemical functionalization and supramolecular chemistry of M@C(82). Selective functionalization and successful structural analysis of derivatives have revealed their chemical features arising from endohedral metal doping.
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