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Title: Iron-catalyzed preparation of trifluoromethyl substituted vinyl- and alkynylcyclopropanes. Author: Morandi B, Cheang J, Carreira EM. Journal: Org Lett; 2011 Jun 17; 13(12):3080-1. PubMed ID: 21591649. Abstract: A convenient iron-catalyzed procedure to prepare trifluoromethylated vinyl- and alkynylcyclopropanes in a chemo- and diastereoselective manner is presented. The active diazo compound (trifluoromethyl diazomethane) is generated in situ and used in the concomitant cyclopropanation reaction.[Abstract] [Full Text] [Related] [New Search]