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  • Title: Star-Shaped Polyacrylates: Highly Functionalized Architectures via CuAAC Click Conjugation.
    Author: Lammens M, Fournier D, Fijten MW, Hoogenboom R, Prez FD.
    Journal: Macromol Rapid Commun; 2009 Dec 01; 30(23):2049-55. PubMed ID: 21638494.
    Abstract:
    Well-defined functional star-shaped polymer structures with up to 29 arms have been successfully synthesized by the combination of atom transfer radical polymerization (ATRP) and click chemistry. First, azide end-functionalized poly(isobornyl acrylate) (PiBA) star-shaped polymers were prepared by successive ATRP and bromine substitution. Subsequently, alkyne end-functionalized molecules and polymers were introduced onto the star-shaped PiBA bearing pendant azide moieties by copper-catalyzed azide-alkyne cycloaddition (CuAAC). The possibilities and limits for the CuAAC on such highly branched polyacrylates are described.
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