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  • Title: Asymmetric synthesis of the core structure of leucosceptroids A-D.
    Author: Xie J, Ma Y, Horne DA.
    Journal: J Org Chem; 2011 Aug 05; 76(15):6169-76. PubMed ID: 21644513.
    Abstract:
    The asymmetric synthesis of the core structure of leucosceptroids A-D has been achieved. The key steps of the synthesis includes the formation of the cis-2,5-disubstituted THF ring by TPAP catalytic oxidative cyclization followed by a highly diastereoselective intramolecular Diels-Alder reaction to fashion the fused tricyclic hydrindane ring system.
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