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  • Title: Iridium-catalysed condensation of alcohols and amines as a method for aminosugar synthesis.
    Author: Cumpstey I, Agrawal S, Borbas KE, Martín-Matute B.
    Journal: Chem Commun (Camb); 2011 Jul 21; 47(27):7827-9. PubMed ID: 21655585.
    Abstract:
    Primary carbohydrate amines at primary and secondary carbons are alkylated by alcohols in the presence of [Cp*IrCl(2)](2). When primary carbohydrate alcohols are used as the coupling partners and in the presence of Cs(2)CO(3), amine-linked pseudodisaccharides are obtained. Secondary carbohydrate alcohols are unaffected under these conditions, which allows regioselective reactions.
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