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  • Title: Palladium-catalyzed C-S coupling: access to thioethers, benzo[b]thiophenes, and thieno[3,2-b]thiophenes.
    Author: Kuhn M, Falk FC, Paradies J.
    Journal: Org Lett; 2011 Aug 05; 13(15):4100-3. PubMed ID: 21732682.
    Abstract:
    The first C-S bond formation/cross-coupling/cyclization domino reaction using thiourea as a cheap and easy to handle dihydrosulfide surrogate has been developed. Structurally important biarylthioether, benzo[b]thiophenes, and thieno[3,2-b]thiophene scaffolds are provided in high yield.
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