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  • Title: Highly active organocatalysts for asymmetric anti-Mannich reactions.
    Author: Martín-Rapún R, Fan X, Sayalero S, Bahramnejad M, Cuevas F, Pericàs MA.
    Journal: Chemistry; 2011 Aug 01; 17(32):8780-3. PubMed ID: 21735502.
    Abstract:
    Lighten the load! A family of enantiopure 4-oxy-substituted 3-aminopyrrolidines arising from the enantioselective ring-opening of meso-3-pyrroline oxide have been developed as catalysts for the asymmetric, anti-selective Mannich reaction (see scheme; PMP=p-methoxyphenyl; PG=protecting group). Very high catalytic activity (down to 0.01 mol % loading) and stereoselectivity have been recorded.
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