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  • Title: Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis.
    Author: Kim JH, Lee SH, Lee JS, Lee M, Park CB.
    Journal: Chem Commun (Camb); 2011 Oct 07; 47(37):10227-9. PubMed ID: 21748164.
    Abstract:
    Among the porphyrin molecules with different metal insertion sites and functional ligands, Zn-porphyrin most efficiently regenerates NADH through photo-induced electron transfer in the presence of [Cp*Rh(bpy)H(2)O](2+), a rhodium-based electron mediator. Photochemical regeneration of NADH by Zn-porphyrin is successfully coupled with redox enzymatic synthesis under dark state conditions.
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