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  • Title: Functionalized flexible MOFs as fillers in mixed matrix membranes for highly selective separation of CO2 from CH4 at elevated pressures.
    Author: Zornoza B, Martinez-Joaristi A, Serra-Crespo P, Tellez C, Coronas J, Gascon J, Kapteijn F.
    Journal: Chem Commun (Camb); 2011 Sep 07; 47(33):9522-4. PubMed ID: 21769350.
    Abstract:
    Mixed matrix membranes (MMMs) composed of a glassy polymer (polysulfone) and the flexible metal organic framework NH(2)-MIL-53(Al) exhibit excellent separation properties. In contrast to most reported membranes, CO(2)/CH(4) separation selectivity increases with pressure, related to the flexibility of the filler.
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