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  • Title: N-tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions.
    Author: Shao Z, Zhang H.
    Journal: Chem Soc Rev; 2012 Jan 21; 41(2):560-72. PubMed ID: 21785803.
    Abstract:
    Transition metal-catalyzed cross-coupling reactions have been established as one of the most powerful tools for the construction of C-C and C-X bonds. In this context, the development of novel metal-catalyzed cross-coupling processes that do not require stoichiometric organometallic reagents is particularly attractive. Recently, N-tosylhydrazones have emerged as a new type of versatile coupling partners for transition metal-catalyzed cross-coupling reactions as well as metal-free cross-coupling reactions, and have attracted increasing attention. This tutorial review summarizes recent important developments in this area with N-tosylhydrazones as versatile coupling partners.
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