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  • Title: Enantioselective formal synthesis of palmerolide A.
    Author: Prasad KR, Pawar AB.
    Journal: Org Lett; 2011 Aug 19; 13(16):4252-5. PubMed ID: 21793548.
    Abstract:
    Enantioselective formal synthesis of macrolactone palmerolide A, a polyketide marine natural product, is described. Key strategies in the synthesis include the oxidative furan ring-opening of a chiral furyl carbinol for the installation of the 1,4-dienol core and a Jung nonaldol-aldol reaction for the dienamide core.
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