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  • Title: Nickel-Catalyzed Coupling Reactions of Alkenes.
    Author: Ng SS, Ho CY, Schleicher KD, Jamison TF.
    Journal: Pure Appl Chem; 2008; 80(5):929-939. PubMed ID: 21814295.
    Abstract:
    Several reactions of simple, unactivated alkenes with electrophiles under nickel(0) catalysis are discussed. The coupling of olefins with aldehydes and silyl triflates provides allylic or homoallylic alcohol derivatives, depending on the supporting ligands and, to a lesser extent, the substrates employed. Reaction of alkenes with isocyanates yields N-alkyl acrylamides. In these methods, alkenes act as the functional equivalents of alkenyl- and allylmetal reagents.
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