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  • Title: Kinetic resolution of N-acyl-β-lactams via benzotetramisole-catalyzed enantioselective alcoholysis.
    Author: Bumbu VD, Birman VB.
    Journal: J Am Chem Soc; 2011 Sep 07; 133(35):13902-5. PubMed ID: 21823609.
    Abstract:
    The first nonenzymatic kinetic resolution of β-lactams has been achieved. Alcoholysis of their N-aroyl derivatives in the presence of a simple chiral acyl transfer catalyst, benzotetramisole, produces β-amino acid derivatives with excellent enantioselectivity.
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