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  • Title: Pyridinium-based symmetrical diamides as chemosensors in visual sensing of citrate through indicator displacement assay (IDA) and gel formation.
    Author: Ghosh K, Ranjan Sarkar A.
    Journal: Org Biomol Chem; 2011 Oct 07; 9(19):6551-8. PubMed ID: 21829838.
    Abstract:
    The design and synthesis of pyridinium-based symmetrical diamides 1 and 2 along with their anion binding studies through 'indicator-diplacement assay' are reported. Both the chemosensors effectively respond in in CH(3)CN-H(2)O (4 : 1 v/v) at pH = 6.3 for the selective naked-eye detection of citrate. Additionally, chemosensor 2 (c = 6.29 × 10(-3) M) forms a stable gel only with citrate in CH(3)CN, which validates its visual sensing.
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