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  • Title: A homometallic tricapped cubane cluster: [(Cp*Mo)4B4H4(μ4-BH)3] (Cp* = η5-C5Me5).
    Author: Thakur A, Sahoo S, Ghosh S.
    Journal: Inorg Chem; 2011 Sep 05; 50(17):7940-2. PubMed ID: 21834507.
    Abstract:
    The reaction of [Cp*MoCl(4)] with an excess of LiBH(4), followed by thermolysis with tellurium powder in toluene, afforded a tricapped cubane cluster, [(Cp*Mo)(4)B(4)H(4)(μ(4)-BH)(3)] (1), which represents an unprecedented metal-rich metallaborane cluster with a cubane core containing 58 cluster valence electrons (cve) and three metal-metal bonds.
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