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  • Title: Readily accessible chiral diene ligands for Rh-catalyzed enantioselective conjugate additions of boronic acids.
    Author: Trost BM, Burns AC, Tautz T.
    Journal: Org Lett; 2011 Sep 02; 13(17):4566-9. PubMed ID: 21834567.
    Abstract:
    Enabled by the broad scope of the Pd-catalyzed asymmetric alkylation of meso- and d,l-divinylethylene carbonate, several chiral diene ligands were prepared in two steps from commercial materials. Subsequently, these ligands were evaluated in the Rh-catalyzed asymmetric conjugate addition of boronic acids to enones.
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