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  • Title: Direct enantioselective access to 4-substituted tetrahydroquinolines by catalytic asymmetric transfer hydrogenation of quinolines.
    Author: Rueping M, Theissmann T, Stoeckel M, Antonchick AP.
    Journal: Org Biomol Chem; 2011 Oct 07; 9(19):6844-50. PubMed ID: 21837348.
    Abstract:
    A convenient protocol for the enantioselective synthesis of 4-substituted tetrahydroquinolines has been developed. Chiral BINOL phosphoric acids promote the reduction of a wide range of 4-substituted quinolines with Hantzsch esters with good to high levels of enantioselectivity.
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