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  • Title: Synthesis and reactivity of a uranyl-imidazolyl complex.
    Author: Schettini MF, Wu G, Hayton TW.
    Journal: Chem Commun (Camb); 2012 Feb 01; 48(10):1484-6. PubMed ID: 21858329.
    Abstract:
    Treatment of [UO(2)(Ar(2)nacnac)Cl](2) with 4 equiv. of Li(C(4)H(5)N(2)) results in the formation of a rare uranyl organometallic complex [Li(MeIm)][UO(μ-O)(Ar(2)nacnac)(μ-C,N-C(4)H(5)N(2))(2)] (2), in moderate yield. Reaction of 2 with 1 equiv. of MCl(2) (M = Fe, Co) yields the bimetallic complexes [MCl(MeIm)][UO(2)(Ar(2)nacnac)(μ-N,C-C(4)H(5)N(2))(2)] (M = Fe, 3; M = Co, 4).
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