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Title: Direct electrochemistry of an [FeFe]-hydrogenase on a TiO2 electrode. Author: Morra S, Valetti F, Sadeghi SJ, King PW, Meyer T, Gilardi G. Journal: Chem Commun (Camb); 2011 Oct 14; 47(38):10566-8. PubMed ID: 21863186. Abstract: [FeFe]-hydrogenases are efficient natural catalysts that can be exploited for hydrogen production. Immobilization of the recombinant [FeFe]-hydrogenase CaHydA was achieved for the first time on an anatase TiO(2) electrode. The enzyme is able to interact and exchange electrons with the electrode and to catalyze hydrogen production with an efficiency of 70%.[Abstract] [Full Text] [Related] [New Search]