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  • Title: Tandem reactions of 1,2-allenic ketones leading to substituted benzenes and α,β-unsaturated nitriles.
    Author: Zhang X, Jia X, Fang L, Liu N, Wang J, Fan X.
    Journal: Org Lett; 2011 Oct 07; 13(19):5024-7. PubMed ID: 21877737.
    Abstract:
    One-pot double Michael addition/intramolecular aldol reaction/decarboxylation of 1,2-allenic ketones with cyanoacetate offers an efficient and convenient approach to highly functionalized benzenes. With 2-substituted cyanoacetates, the reaction proceeds via a different tandem process to afford α,β-unsaturated nitriles effectively.
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