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  • Title: Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities.
    Author: Meng X, Qin C, Wang XL, Su ZM, Li B, Yang QH.
    Journal: Dalton Trans; 2011 Oct 21; 40(39):9964-6. PubMed ID: 21904746.
    Abstract:
    Immobilization of the chiral salen-metal complex [Mn(III)(salen)(H(2)O)(2)ClO(4)] on the Keggin-type polyoxometalate (POM) skeletons leads to the isolation of POM derivatives functionalized with chiral salen-metal complexes, which represent the first examples of introducing chiral salen-metal complexes into the POM systems.
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