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  • Title: Effect of nitro groups on the photo physical properties of benzimidazolone: a solvatochromic study.
    Author: Madhura V, Kulkarni MV, Badami S, Yenagi J, Tonannavar J.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2011 Dec 15; 84(1):137-43. PubMed ID: 21968209.
    Abstract:
    Electronic absorption and fluorescence spectra of mono, di, and tri-nitro benzimidazolones are measured at room temperature (298 K) in nine solvents with different polarities and the observed shifts are compared with benzimidazolone. Ground and excited state electric dipole moments are determined using the solvatochromic method based on the bulk solvent properties, F(1)(ε, n) and F(2)(ε, n). A reasonable agreement is observed between the experimental and ab initio dipole moments. Change in dipole moment is also determined using the solvatochromic method based on the microscopic solvent polarity parameter, (E(T)(N)), which considers the polarization changes due to hydrogen bonding in different solvents. It has been observed that the correlation of the solvatochromic Stokes shifts with the parameter (E(T)(N)), is superior to that derived using bulk solvent polarity functions for all the benzimidazolones reported in the present study. Calculated difference between excited state and ground state dipole moments seems to be a good measure of the effect of nitro group when correlated with (E(T)(N)).
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