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  • Title: Copper(I) catalyzed regioselective asymmetric alkoxyamination of aryl enamide derivatives.
    Author: Nakanishi M, Minard C, Retailleau P, Cariou K, Dodd RH.
    Journal: Org Lett; 2011 Nov 04; 13(21):5792-5. PubMed ID: 21973176.
    Abstract:
    The copper(I) catalyzed reaction of an enamide with an iminoiodane, in the presence of an alcohol, triggers the direct alkoxyamination of the double bond. This transformation represents a straightforward access to α-amino aminals in a completely regio- and diastereoselective manner. Use of a chiral Box ligand allows this reaction to be carried out in an enantioselective fashion.
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