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  • Title: Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins.
    Author: Wang X, Buchwald SL.
    Journal: J Am Chem Soc; 2011 Nov 30; 133(47):19080-3. PubMed ID: 22035143.
    Abstract:
    The first method for the highly enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted olefins has been developed. By employing either of the P-chirogenic phosphine ligands BenzP* and QuinoxP*, linear aldehydes with β-chirality can be prepared in a highly enantioselective fashion with good chemo- and regioselectivities.
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