These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: Solvent effect on the absorption and fluorescence of ergone: determination of ground and excited state dipole moments.
    Author: Liu L, Sun Y, Wei S, Hu X, Zhao Y, Fan J.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2012 Feb; 86():120-3. PubMed ID: 22047993.
    Abstract:
    The effect of solvents on the absorption and emission spectra of ergone has been studied in various solvents at 298 K. The bathochromic shift was observed in absorption and fluorescence spectra with the increase of solvents polarity, which implied that transition involved was π→π*. And the normalized transition energy value E(T)(N) showed some scattering when plotted versus Δν. The ground state and excited state dipole moments were calculated by quantum-mechanical second-order perturbation method as a function of the dielectric constant (ε) and refractive index (n). The result was found to be 1.435 D and 2.520 D in ground state and excited state respectively. And also, the density functional calculations were used to obtain the ground state and excited state dipole moments for it has proven to be suitable for calculating electronic excitation energy. And the result is consistent with the experimental.
    [Abstract] [Full Text] [Related] [New Search]