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  • Title: C-N bond cleavage of allylic amines via hydrogen bond activation with alcohol solvents in Pd-catalyzed allylic alkylation of carbonyl compounds.
    Author: Zhao X, Liu D, Guo H, Liu Y, Zhang W.
    Journal: J Am Chem Soc; 2011 Dec 07; 133(48):19354-7. PubMed ID: 22050268.
    Abstract:
    Hydrogen-bond-activated C-N bond cleavage of allylic amines was realized in Pd-catalyzed allylic alkylation to form the C-C bond product. The method could be expanded to a series of allylic amines and carbonyl compounds with excellent results. It provides a new and convenient access to C-C bond formation based on Pd-catalyzed allylic alkylation of allylic amines by using only inexpensive alcohol solvents.
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