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  • Title: Ruthenium-catalyzed C-H/N-O bond functionalization: green isoquinolone syntheses in water.
    Author: Ackermann L, Fenner S.
    Journal: Org Lett; 2011 Dec 16; 13(24):6548-51. PubMed ID: 22077379.
    Abstract:
    Ruthenium-catalyzed isoquinolone syntheses with ample scope were accomplished through carboxylate assistance in environmentally benign water as a reaction medium. The high chemoselectivity of the ruthenium(II) carboxylate complex also set the stage for the direct use of free hydroxamic acids for annulations of alkynes.
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