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  • Title: Aluminepin: aluminum analogues of borepin and gallepin.
    Author: Yoshida K, Furuyama T, Wang C, Muranaka A, Hashizume D, Yasuike S, Uchiyama M.
    Journal: J Org Chem; 2012 Jan 06; 77(1):729-32. PubMed ID: 22106921.
    Abstract:
    We report synthesis of dibenzoaluminepin as the first aluminepin, an aluminum analogue of borepin and gallepin. This compound contains one molecule of ethereal solvent on the Al atom, which adopts a tetrahedral geometry. The central 7-membered aluminepin ring has a boatlike conformation and was characterized by single-crystal X-ray diffraction, (1)H/(13)C NMR, and DFT studies. In addition, NICS, NBO, and theoretical calculations provide insight into the nature of the bonding and aromaticity of aluminepins.
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