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  • Title: Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide.
    Author: Gao Y, Li Y, Zhang L, Huang H, Hu J, Shah SM, Su X.
    Journal: J Colloid Interface Sci; 2012 Feb 15; 368(1):540-6. PubMed ID: 22138269.
    Abstract:
    Significant concerns have been raised over pollution of antibiotics including tetracyclines in aquatic environments in recent years. Graphene oxide (GO) is a potential effective absorbent for tetracycline antibiotics and can be used to remove them from aqueous solution. Tetracycline strongly deposited on the GO surface via π-π interaction and cation-π bonding. The adsorption isotherm fits Langmuir and Temkin models well, and the theoretical maximum of adsorption capacity calculated by Langmuir model is 313 mg g(-1), which is approximately in a close agreement with the measured data. The kinetics of adsorption fits pseudo-second-order model perfectly, and it has a better rate constant of sorption (k), 0.065 g mg(-1) h(-1), than other adsorbents. The adsorption capacities of tetracycline on GO decreased with the increase in pH or Na(+) concentration. The adsorption isotherms of oxytetracycline and doxycycline on GO were discussed and compared.
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