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  • Title: Enantioselective palladium-catalyzed [3 + 2] cycloadditions of trimethylenemethane with nitroalkenes.
    Author: Trost BM, Bringley DA, Seng PS.
    Journal: Org Lett; 2012 Jan 06; 14(1):234-7. PubMed ID: 22176260.
    Abstract:
    Nitroalkenes readily undergo palladium-catalyzed [3 + 2] cycloaddition with trimethylenemethane to generate nitrocyclopentanes in excellent yield and enantioselectivity. Furthermore, the products thus formed are highly versatile synthetic intermediates and provide convenient access to both cyclopentylamines and cyclopentenones.
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