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  • Title: Cu-catalyzed asymmetric [3+2] cycloaddition of α-iminoamides with activated olefins.
    Author: González-Esguevillas M, Adrio J, Carretero JC.
    Journal: Chem Commun (Camb); 2012 Feb 18; 48(15):2149-51. PubMed ID: 22246428.
    Abstract:
    A variety of 2-amido pyrrolidines, including Weinreb-type amides, have been prepared with very high exo diastereoselectivity and enantioselectivitiy in the reaction of α-iminoamides with activated alkenes catalyzed by Cu(I)-Segphos ligands.
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