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  • Title: A novel entry to functionalized benzofurans and indoles via palladium(0)-catalyzed arylative dearomatization of furans.
    Author: Yin B, Cai C, Zeng G, Zhang R, Li X, Jiang H.
    Journal: Org Lett; 2012 Feb 17; 14(4):1098-101. PubMed ID: 22316069.
    Abstract:
    A novel entry to functionalized benzofurans and indoles from furans in moderate to good yields has been developed. This protocol involves palladium(0)-catalyzed dearomatizing intramolecular arylation of the furan ring, formation of a π-allylic palladium complex, furan ring opening, and a β-hydride elimination sequence.
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